New step to new energetics - Judbbarovski process.

New step to new energetics - Judbarovski process

Detailed Description  

Economics of the said invention is tremendous. Here I consider Opex only (Operational expenditures) to estimate, while Capex (Capital expenditures) is ordinary, because is used ordinary, conventional, not sophisticated apparatus. 

Claim 1. Fischer-Tropsch process (Germany, a middle of 1920-th) to produce motors' fuels from carbon based fuels (e.g. coals, lignite or others ones) and the water vapor, C(s) + H2O(g) = CO + H2, named by "syngas", to produce the oil, CO + 2H2 = CH2 + H2O, is combined with Boudouard reaction (France, 1905) converting carbon monoxide into carbon dioxide + graphite, CO = 0.5 × (CO2 + C) at quite mild conditions, and totally balanced in 1.5 C + H2O = CH2 + 0.5 CO2, manufacturing the oil.  

Indeed. 

2C + 2H2O = CO + CO +2H2 = CO + CH2 + H20 (Fischer-Tropsch process) and in separate reactor CO = 0.5 × (CO2 + C) (Boudouard reversible reaction at quite mild conditions), so totally

1.5 C + H2O = CH2 + 0.5 CO2, named by Judbarovski process (Israel, 2023) to underline its patentability.

It alone allows to save 25 % carbon based fuels - C and 50% harmful exhaust CO2, but needs additional energy ~40 kJ from O.1 C combustion, so it is resulted into

1.6 C + H2O = CH2 + 0.6 CO2

Supposing a domestic costs in Central Europe as USD 100.O / ton C, and USD 30.0 / ton CO2, 

CH2 is (1.6 × 12 × 100 - 0.6 × 44 × 30) ÷ 14 = USD 80/ ton CH2, or incredible USD 11.5/bbl vs. 75.0 as world market prices 2023/24 and many years earlier.

Claim 2.                                          +

Oil manufactured by Claim 1 is decomposed thermally into hydrogen and more clean carbon (graphite) to recycle about 60% of dirty C (carbon) from Judbarovski process of Claim 1. All those allow to produce free hydrogen, because expenses of it can be relayed to carbon product cost painlessly, and further to Judbarovski process of Claim 1 now with carbon in much more clean form and about at half cheapening additionally the said Judbarovski process , but doesn't need in new sites exploration, heavy mining, and long transportation for delivery.

Claim 3. Carbon dioxide as a byproduct of Judbarovski process and free hydrogen produced correspondently to Claim 2, can incredibly save expenditures for raw materials for gas manufacturing by Sabatier process - CO2 + 4 H2 = CH4 + 2 H2O.

So such gas product is much cleaner and at a half cheaper than cheapest long term world prices of natural gas, and in order of magnitude cheaper than it is and was asked by a cartel of natural gas exporters. 

Additional cheapening of gas allows the claim 4. 

Claim 4, is the Claim 3, herein CO2 can be extracted from the air everywhere in the world, when CO2 diffuses from the air and then diffused much more slowly through the water surface of water pond/ponds, and reacting with  Ca(OH)2  water solution creating CaCO3' sediment on the said pond/ponds bottom and extracted for thermal decomposition in CO2 and in CaO going to be desolved in the water and return back in the said pond/ponds. Totally about 300 km2 of such ponds is enough to satisfy all world energy consume of present mankind in cheap and clean coal, oil and gas.

Claim 5. Oil and gas of Claim 1, Claim 3 and Claim 4, and hydrogen and carbon (graphite) of Claim 2 can be abundant and inexhausted very attractive cheap and clean raw material for chemistry. For example, ammonia, produced by classical Haber-Bosh process, can be practically free by Opex, while a long term world market prices are and were some hundreds US dollars for a ton, reaching 1000 and even more. 

Claim 6. Clean carbon of Claim 2 can be used to produce solar cells.

Claim 7. Integration of huge wind and solar energy in national grids now is and was unsolvable problem.

The cheap fuels manufactured following Claim 1, Claim 2, Claim 3, Claim 4 separately or in their different combinations can be used to support and help renewables as heat as electricity to satisfy any designed schedule of energy supply distributed for distributed consumers, and to satisfy reliability too, if wartimes or against terrorist attack or so.